Nanjing Chemical Material Corp.
Service
Products

How Is Ethyl Bromide Prepared From Ethyl Alcohol How Is Ethyl Bromide Prepared From Ethyl Alcohol

1. The Formation of Ethyl Bromide

10 mL of 95% ethanol and 9 mL of water are added to a 100 mL round bottom flask. Under constant shaking and cooling, 19 mL of concentrated sulfuric acid is slowly added. The mixture is cooled to room temperature. The finely divided 15 g of sodium bromide is added with stirring, and a few additional zeolites are added. Carefully shake the flask to make it even. The lower end of the condenser tube is connected to the lead pipe. Ethyl bromide has a very low boiling point and is extremely volatile. To avoid losses, cold water and 5 mL of saturated sodium bisulfite solution are added to the receiver. Cool in an ice water bath and allow the end of the receiving tube to be submerged in the aqueous solution. Start heating on low heat, make the reaction liquid boil slightly, and let the reaction proceed smoothly until no ethyl bromide is flowing out. (As the reaction proceeds, the reaction mixture begins to have a large amount of gas. At this time, the heating intensity must be controlled. Do not cause bumping and then the solid gradually decreases. When the solids disappear completely, the reaction solution becomes viscous and then becomes a transparent liquid. Now it is near the end of the reaction. Check the presence or absence of ethyl bromide in a beaker containing water.

2. Purification of Ethyl Bromide

Pour the liquid from the receiver into the separatory funnel. After static stratification, transfer the crude ethyl bromide below to the dry conical flask. Under the cooling of ice water, carefully add 1 ~ 2mL concentrated sulfuric acid, while shaking the cone to cool. The lower concentrated sulfuric acid is separated by a dry separatory funnel. The upper layer of ethyl bromide is poured from a tapping funnel into a 50 mL flask, and several zeolites are added for distillation. Since the boiling point of ethyl bromide is very low, the receiver should be cooled in ice water. Accept the fraction of 37 ~ 40 °C. The yield is about 10 g (The yield is about 54%).

Pure ethyl bromide is a colorless liquid with a boiling point of 38.4 °C and nD 20 = 1.4239

Note: If the reaction mixture is not shaken before heating, the reaction is prone to bumping and the reaction fails. When starting the reaction, heat it with a small heat to avoid the escape of hydrogen bromide. When adding concentrated sulfuric acid, be sure to pay attention to cooling to avoid the loss of ethyl bromide. The experiment process uses two liquid separations, the first time to retain the lower layer, and the second time to the upper layer product. During the reaction, neither the reaction time is enough, nor the distillation time is too long. The water is over-distilled to cause the sodium sulfate to solidify in the flask.

Ethyl bromide

Related Products Wiki
  • The Preparation Method of Bronopol

    The Preparation Method of Bronopol

    October 30, 2020Bronopol can be obtained by two reactions of alkanes hydroxylation and bromination with nitromethane and formaldehyde as raw materials and under alkaline conditions. The reaction equations are as foll...view
  • The Role of Expandable Microspheres in Automotive Lightweighting

    The Role of Expandable Microspheres in Automotive Lightweighting

    November 2, 2023The automotive industry is in the midst of a significant transformation, driven by the pursuit of increased fuel efficiency, reduced emissions, and enhanced performance. One of the key strategies empl...view
  • An Introduction of Hexyl Bromide

    An Introduction of Hexyl Bromide

    September 24, 2020Hexyl bromide is a transparent or light-yellow liquid with a pungent odor. It is insoluble in water but soluble in alcohols, ethers and esters.Hexyl bromide should be stored in a cool, ventilated ware...view
  • Sustainable Approaches to Utilizing 1,2-Epoxybutane

    Sustainable Approaches to Utilizing 1,2-Epoxybutane

    January 26, 2024In recent years, there has been a growing concern about the environmental impact of various industries. As a result, many companies are now exploring sustainable approaches in their production process...view
  • Applications of n-butylene-1,2-oxide in the petrochemical industry

    Applications of n-butylene-1,2-oxide in the petrochemical industry

    November 2, 2023The petrochemical industry is a vast and multifaceted sector that plays a crucial role in providing raw materials for a wide range of products we use in our daily lives. One lesser-known but highly im...view
  • What Chemicals Can the Ethyl Vinyl Ether React with

    What Chemicals Can the Ethyl Vinyl Ether React with

    October 30, 2020In organic synthesis, ethyl vinyl ether is mainly used as a protecting group for hydroxide radical and a transfer reagent for vinyl, in addition, it can participate in cycloaddition reaction.Among var...view
Related Products
  • C20-C24 alkylbenzene Product InformationProduct Name: C20-C24 alkylbenzeneChemical Formula: CAS No.: Dangerous Grade: Technical Data: ITEMSRESULTSAppearanceConformsColor(ASTM)≤0.5Density(20℃),g/cm30.8525Bromine number, gBr/...
  • 3-Methacryloxypropyltrimethoxysilane Product Name: 3-MethacryloxypropyltrimethoxysilaneChemical Formula: C10H20O5SiCAS No.: 2530-85-0Dangerous Grade: 3Technical Data of 3-MethacryloxypropyltrimethoxysilaneITEMSSPECIFICATIONAppearanceCol...
  • Butyl Vinyl Ether Product Name: Butyl Vinyl EtherChemical Formula: C6H12OCAS No.: 111-34-2Dangerous Grade: 3Technical Data of Butyl Vinyl EtherItemSpecificationAppearanceColorless Transparent LiquidAssay≥99.0%Water Co...
  • Methyl 2-Chloropropionate Product InformationProduct Name: Methyl 2-ChloropropionateChemical Formula: C4H7ClO2CAS No.: 17639-93-9Dangerous Grade: 3Technical Data:ITEMSSPECIFICATIONSAppearanceColorless clear liquidAssay, %≥99....
  • TEL:+86-25-52337978
  • EMAIL: info@njchm.com
  • ADDRESS:12/F, Block B, Technology and Innovation Building, Nanjing University of Technology, No.5 New Model Road, Nanjing 210009, China