Nanjing Chemical Material Corp.
Service
Products

How Is Ethyl Bromide Prepared From Ethyl Alcohol How Is Ethyl Bromide Prepared From Ethyl Alcohol

1. The Formation of Ethyl Bromide

10 mL of 95% ethanol and 9 mL of water are added to a 100 mL round bottom flask. Under constant shaking and cooling, 19 mL of concentrated sulfuric acid is slowly added. The mixture is cooled to room temperature. The finely divided 15 g of sodium bromide is added with stirring, and a few additional zeolites are added. Carefully shake the flask to make it even. The lower end of the condenser tube is connected to the lead pipe. Ethyl bromide has a very low boiling point and is extremely volatile. To avoid losses, cold water and 5 mL of saturated sodium bisulfite solution are added to the receiver. Cool in an ice water bath and allow the end of the receiving tube to be submerged in the aqueous solution. Start heating on low heat, make the reaction liquid boil slightly, and let the reaction proceed smoothly until no ethyl bromide is flowing out. (As the reaction proceeds, the reaction mixture begins to have a large amount of gas. At this time, the heating intensity must be controlled. Do not cause bumping and then the solid gradually decreases. When the solids disappear completely, the reaction solution becomes viscous and then becomes a transparent liquid. Now it is near the end of the reaction. Check the presence or absence of ethyl bromide in a beaker containing water.

2. Purification of Ethyl Bromide

Pour the liquid from the receiver into the separatory funnel. After static stratification, transfer the crude ethyl bromide below to the dry conical flask. Under the cooling of ice water, carefully add 1 ~ 2mL concentrated sulfuric acid, while shaking the cone to cool. The lower concentrated sulfuric acid is separated by a dry separatory funnel. The upper layer of ethyl bromide is poured from a tapping funnel into a 50 mL flask, and several zeolites are added for distillation. Since the boiling point of ethyl bromide is very low, the receiver should be cooled in ice water. Accept the fraction of 37 ~ 40 °C. The yield is about 10 g (The yield is about 54%).

Pure ethyl bromide is a colorless liquid with a boiling point of 38.4 °C and nD 20 = 1.4239

Note: If the reaction mixture is not shaken before heating, the reaction is prone to bumping and the reaction fails. When starting the reaction, heat it with a small heat to avoid the escape of hydrogen bromide. When adding concentrated sulfuric acid, be sure to pay attention to cooling to avoid the loss of ethyl bromide. The experiment process uses two liquid separations, the first time to retain the lower layer, and the second time to the upper layer product. During the reaction, neither the reaction time is enough, nor the distillation time is too long. The water is over-distilled to cause the sodium sulfate to solidify in the flask.

Ethyl bromide

Related Products Wiki
  • The Effect of Glycolic Acid in Beauty and Skin Care

    The Effect of Glycolic Acid in Beauty and Skin Care

    May 17, 2022Glycolic acid is an organic substance with the chemical formula C2H4O3, a colorless and deliquescent crystal. Soluble in water, soluble in methanol, ethanol, ethyl acetate and other organic solvents, ...view
  • Preservative Effect of Cocoamido Propil Betaina

    Preservative Effect of Cocoamido Propil Betaina

    May 17, 2021Cocoamido propil betaina, also known as coconut betaine (abbreviated CAPB), is a coconut oil derivative that is a viscous yellow liquid produced when raw coconut oil is mixed with a naturally derived ...view
  • Composite Additive of Trace Elements

    Composite Additive of Trace Elements

    October 13, 2021In composite additive of trace elements, the proportion of trace elements such as copper, zinc, manganese, iron, iodine, selenium and cobalt is reasonable and scientific, and exists in the form of ami...view
  • Cocoamido Propil Betaina in Cosmetics

    Cocoamido Propil Betaina in Cosmetics

    May 17, 2021Cocoamido propil betaina is an amphoteric surfactant that is water soluble, minimally irritating, acid and alkali stable and, most importantly, very foaming and highly effective at removing limescale....view
  • Polymer polyol

    Polymer polyol

    July 19, 2024Polymer polyol, also known as vinyl polymer graft polyether polyol, referred to as POP, the appearance is generally white or light milky yellow, is a kind of polyol containing organic fillers, which c...view
  • Amyl Salicylate

    Amyl Salicylate

    October 13, 2021Amyl salicylate is a chemical with the formula C12H16O3. It is used for making soap and edible fragrance.Amyl salicylate is one of the common and important salicylate esters. It is suitable for grass ...view
Related Products
  • Linear Alkyl Benzene Product Name: Linear Alkyl BenzeneChemical Formula: C16H26CAS No.: 129813-58-7Dangerous Grade: Not regulated as dangerous chemicalTechnical Data:Standard: GB/T5177-2017ItemLimitsTest MethodAppearanceC...
  • Ethyl Vinyl Ether Product Name: Ethyl Vinyl EtherChemical Formula: C4H8OCAS No.: 109-92-2Dangerous Grade: 3Technical Data of Ethyl Vinyl EtherItemSpecificationAppearanceColorless Transparent LiquidAssay≥99.50%Water C...
  • DL-1,2-hexanediol Product InformationProduct Name: DL-1,2-hexanediolChemical Formula: C6H14O2CAS No.: 6920-22-5Dangerous Grade: Technical Data: ITEMSSPECIFICATIONAppearanceColorless clear liquidColor≤20Assay(G.C)≥99....
  • Fully-refined Paraffin Wax Product Name: No.54 fully-refined paraffin waxChemical Formula: CAS No.: NoneDangerous Grade: Technical Data: ITEMSRESULTSMelting point ℃ ≥54-56Oil content (mass fraction)% ≤0.8Color/S...
  • TEL:+86-25-52337978
  • EMAIL: info@njchm.com
  • ADDRESS:12/F, Block B, Technology and Innovation Building, Nanjing University of Technology, No.5 New Model Road, Nanjing 210009, China